Platinum is a stable element Word Platinum comes from Spanish word Platina, which means little silver. Platinum hexafluoride is the chemical compound with the formula PtF6, and is one of seventeen known binary hexafluorides. It gives a synopsis of the market, outlining its definition, uses, advancements, and production techniques. The element Platinum is extremely rare and is hard to find. CAS No: 13693-05-5; . Platinum Hexafluoride Hexafluoroplatinate Xenon hexafluoroplatinate Xenon Reaction with liquid water is violent forming HF, oxygen, lower fluorides of platinum, and other products. The heat of vaporization at the boiling point is 7060 cal mole/sup -1/. The table shows element percentages for PtF6 (platinum hexafluoride). Other data available: Vibrational and/or electronic energy levels. Platinum hexafluoride -PtF 6. platinum hexafluoride. Oxides. All rights reserved. Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. It is formed by reacting platinum hexafluoride with relatively uncationisable elements and compounds, for example with xenon to form "XePtF Platinum hexafluoride is the chemical compound with the formula Pt F 6. It is a dark-red volatile solid that forms a dark red gas. Copyright 1993-2022 Mark Winter [ The University of Sheffield and WebElements Ltd, UK]. Platinum. Uses Platinum hexafluoride does not have many commercial applications. The interaction of chlorine with the third-series transition metal hexafluorides has been investigated. PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine National Institutes of Health Platinum hexafluoride forms compounds with molecular oxygen and xenon, [O2+][PtF6 -] and XePtF6 , respectively. A preparation of "XePtF 6 " in HF solution results in a solid which has been characterized as a [PtF 5] polymeric network associated with XeF +. Platinum Hexafluoride . Notes. The material usually has a low level of radioactivity with the chemical hazard greatly exceeding the radiation hazard for all but highly enriched materials. This univalent poisonous gaseous halogen element of the periodic table forms a vast number of compounds with the other chemical elements, even with the noble gases krypton, xenon, and radon. Formula: F 6 Ir. The heat of transition is 2140 cal mole/sup -1/ and the heat of fusion is 1080 cal mole/sup -1/. The compound is a unique example of platinum in the +6 oxidation state. platinum hexafluoride (CAS No. [1], PtF6 was first prepared by reaction of fluorine with platinum metal. PtO 2 and the less common PtO both decompose upon heating. 73, 35 (2001)] and also with a well known result concerning magnetic properties, NMR, and Jahn-Teller effect in the systems possessing even number of d electrons. In the present work, a computational thermochemistry study (semiempirical, PM6 method) for platinum hexafluoride (PtF 6) is performed.The gas-phase formation enthalpy ( f H) and electron affinity are calculated and the results compared with the experimental data. Also, it can react explosively with a number of substances. Platinum hexafluoride does not have many commercial applications. 4 /5. A solid transition occurs at 3.0 deg , 32.5 mm pressure and the fusion point is 61.3-, 586 mm. It is a dark-red volatile solid that forms a red gas. This reaction, discovered by Neil Bartlett in 1962, proved that the noble gases are not totally unreactive. Bartlett had recently been doing some work with platinum hexafluoride, a chemical that's such a strong oxidizer that it can oxidize oxygen. Platinum hexafluoride f s the least stable and most reactive of the known hexafluorides. With only four d-electrons, it is paramagnetic with a triplet ground state. 13693-05-5) SDS. The preparation of platinum hexafluoride and its use as a fluorinating agent in a process for separating plutonium from fission products is presented. PtF6 is octahedral in both the solid state and in the gaseous state. Xenon hexafluoroplatinate is the description of the product obtained from the combination of platinum hexafluoride and xenon in an experiment that proved the chemical reactivity of the noble gas es. A weight loss-versus-time curve indicated the presence of 4:1, 3:1 and 2:1 XeF/sub 2//PdF/sub 4/ complexes. 6. Vibrational spectroscopic and other evidence indicates that this solid yields a sequence of products, of which Cl/sub 3//sup +/IrF/sub 6//sup -/, Cl/sub 3//sup +/Ir/sub 2/F/sub 11//sup -/ and Ir/sub 4/F/sub 20/ have been identified, the last being the ultimate solid product of the room temperature decomposition of the adduct. Formula: Key datasets Brief Profile REACH registered substance factsheets Inventory Biocidal active substance factsheets Regulatory Obligations Regulatory context [Xe complexes with Pt, Pd fluorides; Chlorine-2 oxidation by transition metal hexafluorides], PLATINUM HEXAFLUORIDE AND METHOD OF FLUORINATING PLUTONIUM CONTAINING MIXTURES THERE-WITH. The formula was established by chemical analyses and vapor density. Platinum hexafluoride was obtained from Ozark-Mahoning Company, Tulsa, Oklahoma. A new chlorine fluoride generated in the room temperature decomposition of Cl/sub 2/IrF/sub 6/ has been tentatively formulated as Cl/sub 3/F from infrared evidence. The new compounds XeF/sub 2/.PdF/sub 4/ and XeF/sub 2/.2PdF/sub 4/(XePd/sub 2/F/sub 10/) were produced by interaction of XeF/sub 2/ with either PdF/sub 4/ or Pd/sub 2/F/sub 6/. - Journal of the American Chemical Society. The required PtF5 can be obtained by fluorinating PtCl2: Platinum hexafluoride can gain an electron to form the hexafluoroplatinate anion, PtF The super-oxidising compound was platinum hexafluoride, a yellow-brown solid substance recently discovered by Bernard Weinstock and his colleagues at the Argonne National Laboratory . Krogmann's salt -K 2 Pt(CN) 4 Br. Norman form of the Germanic name Alia, which was a short form of names containing the Germanic element ali meaning 'other'. This market research report India Sulfur Hexafluoride monitors any fresh developments and enhancements. Interestingly, it was a mustard yellow solid compound. Health Issues. References. How to say platinum hexafluoride in English? Platinum hexafluoride is a volatile and unstable dark-red octahedral crystalline compound. Chloroplatinic acid -H 2 PtCl 6. Information on this page: Gas phase ion energetics data. With only four d-electrons, it is paramagnetic with a triplet ground state. Molecular weight: 306.207. Platinum Fluoride is a water insoluble Platinum source for use in oxygen-sensitive applications, such as metal production. It is formed by reacting platinum hexafluoride with relatively uncationisable elements and compounds, for example with xenon to form "XePtF6" (actually a mixture of XeFPtF5, XeFPt2F11, and Xe2F3PtF6), known as xenon hexafluoroplatinate. iii. iv. [2] This route remains the method of choice.[1]. . 0 references . (music) A single or album that has achieved platinum sales, i.e. dark brick red, rhomb solid; strong oxidizing agent; there are also PtF4, 13455-15-7, and PtF5, 13782-84-8 [KIR82], Copyright 2022 ChemicalBook. Consult a physician. publication date. All are aggressive oxidants. Its fame derives from its ability, when in gaseous form and mixed with an excess of xenon, to form XePtF 6 (xenon hexafluoroplatinate). ", Platinum tetrachloride pentahydrate: PtCl, Potassium trichloro(ammine)platinate: K[PtCl, Disodium hexachloroplatinate hexahydrate: Na, Potassium trichloro(ethene)platinate: K[PtCl, Chemical Rubber Company handbook of chemistry and physics, F.A. PtF6 can also be prepared by disproportionation of the pentafluoride (PtF5), with the tetrafluoride (PtF4) as a byproduct. In the solid state, the compound features platinum(IV) in octahedral coordination geometry. The compound is a unique example of platinum in the +6 oxidation state. In 1962, Neil Bartlett used platinum hexafluoride to form a compound between xenon, platinum, and fluorine - xenon hexafluoroplatinate, Xe [PtF 6 ]. Current & Historical Data Worldwide. Difficult (1 votes) Volume 18, Issue 3, March 1986, Pages 235-240. Freebase Data Dumps. This reaction takes place at a temperature of 25-60C, in the atmosphere sulfur hexafluoride. In extremely low concentrations (ppm), fluoride compounds are used in health applications. PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine National Institutes of Health Identifiers CAS Number. With only four d-electrons, it is paramagnetic with a triplet ground state. A preparation of "XePtF 6 " in HF solution results in a solid which has been characterized as a [PtF 5-] n polymeric network associated with XeF +. Formula: F 6 Pt; Molecular weight: 309.074; CAS Registry Number: 13693-05-5; Information on this page: Gas phase ion energetics data; References; Notes; Options: Switch to calorie-based units Platinum hexafluoride (English) quotation. PtF 6 can also be prepared by disproportionation of the pentafluoride (PtF 5 ), with the tetrafluoride (PtF 4 ) as a byproduct. The hexafluoride decomposes on heating; also decomposed by UV radiation to lower fluorides; and reacts with the inert gas xenon, forming a solid product, Xe(PtF6). Angewandte Chemie 1968 , 80 (12) , 453-460. If inhaled. Except where otherwise noted, data are given for materials in their, Drews, T.; Supel, J.; Hagenbach, A.; Seppelt, K. "Solid State Molecular Structures of Transition Metal Hexafluorides", https://en.wikipedia.org/w/index.php?title=Platinum_hexafluoride&oldid=1118573799, Articles with changed ChemSpider identifier, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License 3.0. Clearanc The following are some synonyms of platinum hexafluoride: The oxidation number of platinum in platinum hexafluoride is 6. Select Speaker Voice. A calculated f H(g) value of -669.47 kJ mol-1, in very good agreement with the experimental data from the literature, was . Platinum hexafluoride Periodic table shop Printable periodic table Platinum hexafluoride Pt compounds More compounds. 3PtF : 13693-05-5 Mol. 73, 35 (2001)], where they stated that there is no indication of the structural distortions in PtF{sub 6}. The material was further purified by low temperature distillation according to the procedure described.' The infrared spectrum8 and vapor pressure of the pure material agreed well with the published values. Noun. Finally, in 1962, British chemist Neil Bartlett, working at the University of British Columbia in Vancouver, Canada, succeeded in reacting Xenon with the compound platinum hexafluoride (PtF 6 . PtF6 is octahedral in both the solid state and in the gaseous state. Dark-red octahedral crystals; volatile and unstable; density 3.83g/cm3; melts at 61.3C; vaporizes at 69.14C; reacts violently with water. Platinum hexafluoride. + 27.7758; cubic solid, log P (mm) = 2528.7/ T -4.080 log T + 20.6280; liquid, log P (mm) = --5685.8/T - 27.485 log T + boiling point of the known hexafiuorides. : Platinum Hexafluoride Market 2022 to 2028 Latest Industry Trends, Overview of Segments, New Technology and Growth Analysis - MarketWatch Home Press Release Platinum Hexafluoride Market 2022 to. The results for the platinum compound agree well with the experimentally observed ligand field transition in optical spectra. Microsoft Academic ID. 6" (actually a mixture of XeFPtF The Pt-F bond lengths are 185 picometers. As a reminder, oxidizing agents are chemicals that can strip electrons away from other atoms. 2. See more Chemical formula A chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets . WebElements: THE periodic table on the WWW [www.webelements.com] Pronunciation of platinum hexafluoride with 1 audio pronunciation, 13 translations and more for platinum hexafluoride. platinum hexafluoride Min.Order: 10 Gram FOB Price: USD $ 0.0-0.0/Gram High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. It is a dark-red volatile solid that forms a red gas. : 237-214- CAS no. On Tuesday May 23rd 2006 the American Chemical Society and the Canadian Society for Chemistry recognized the work of Professor Neil Bartlett as an International Historic Chemical Landmark. It reacts with molecular oxygen to produce O2+PtF6 The compound attacks glass at ordinary temperatures. A Xe:PtF/sub 6/ material of approximately 1:1 stoichiometry has been prepared and compared with XePdF/sub 6/(XeF/sub 2/.PdF/sub 4/). 100% (1/1) PtF 6 platinum(VI) fluoride. Chlorine is included in Inorganic Chemicals industry, covered in our Commodity Price Benchmarks. PtF 6 is a strong oxidant and a strong fluorinating agent. PtF6 is a strong fluorinating agent and one of the strongest oxidants, capable of oxidising xenon and O2. It is also used as a cooling gas in gas-cooled atomic reactors as well as a stream gas in gas-fluid chromatography. ELLA. Rev. According to the invention, platinum is reacted with fluorine gas at from 900 to 1100 deg C to form platinum hexafluoride. platinum hexafluoride Chemical Properties,Uses,Production Physical Properties Dark-red octahedral crystals; volatile and unstable; density 3.83g/cm3; melts at 61.3C; vaporizes at 69.14C; reacts violently with water. It is used in research. New!! The oxidation number of platinum in platinum trioxide is 4. It's the 13th most abundant element found in Earth's crust with a concentration of 950 ppm in the upper layers. It is a dark-red volatile solid that forms a red gas. PtF6 is a strong fluorinating agent and one of the strongest oxidants . Fluid helium is frequently used to cool superconducting magnets in atomic magnetic resonance spectrometers. In a preferred embodiment of the invention, embracing the preferred conditions given, anhydrous sulfur tetrafluoride mixed with enough chlorine to react with all elemental sulfur produced is continuously passed at 9001500 C. and ambient pressure through a clean, inert reactor. 1 reference. In vapor phase hydrolysis occurs more smoothly. Platinum hexafluoride is the first simple hexavalent platinum compound that has been prepared. A modern synthesis involves thermal decomposition of platinum hexafluoride. Platinum was discovered by Julius Scaliger in 1735. It is a dark-red volatile solid that forms a red gas. [2] This route remains the method of choice.[1]. The thermal decomposition of XeFPtF/sub 6/ or XePd/sub 2/F/sub 10/ yields highly pure XeF/sub 4/. Sodium hexachloropl -Na 2 PtCl 6. Previous to the experiment with xenon, PtF It is a dark-red volatile solid that forms a red gas. See more Darmstadtium. Xenon react with platinum hexafluoride to produce xenon hexafluoroplatinate (V). However, while teaching at the University of British Columbia, Neil Bartlett discovered that the gas platinum hexafluoride (PtF6) was a powerful oxidizing agent that could oxidize oxygen gas (O2) to form dioxygenyl hexafluoroplatinate (O+ 2 ). Professor Bartlett, working at UBC, demonstrated the first reaction of a noble gas by combining xenon with platinum hexafluoride. Show this safety data sheet to the doctor in attendance. With only four d-electrons, it is paramagnetic with a triplet ground state. 1. The compound is a unique example of platinum in the +6 oxidation state. Die oxidierenden Eigenschaften der Hexafluoride von Elementen der dritten bergangsreihe sowie verwandter Verbindungen. However, it is found mixed in with some other metals such as gold, nickel, and copper. Platinum hexafluoride is the chemical compound with the formula Pt F 6, and is one of seventeen known binary hexafluorides. The required PtF5 can be obtained by fluorinating PtCl2: Platinum hexafluoride can gain an electron to form the hexafluoroplatinate anion, PtF6. However, four-component Dirac molecular Hartree . . Melting point: 25C (decomposes) Boiling point: Density: The following are some synonyms of platinum trioxide: platinum trioxide. This was achieved by burning a platinum wire in a fluorine atmosphere adjacent to a cold surface with yields of up to 70%. With only four d-electrons, it is paramagnetic with a triplet ground state. Platinum hexafluoride 100% (1/1) PtF 6 platinum (VI) fluoride It can be produced by the reaction of dioxygen with platinum hexafluoride. Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. Patent 2,709,186). Platinum is used largely for vehicle emissions control devices. Rev. 2F full record; other . It is also expected to have the same octahedral molecular geometry as PtF 6. The mineralogy of Platinum Localities with greatest number of different Platinum mineral species map should go here 7 6 4 + 5000 km 3000 mi Leaflet | Localities mindat.org, Base map OpenStreetMap Spotted a mistake/omission? 6), known as xenon hexafluoroplatinate. 2F A hexafluoroplatinate is a chemical compound which contains the hexafluoroplatinate PtF 6 anion. Platinum hexafluoride forms compounds with molecular oxygen and xenon, [O2+][PtF6 ] and XePtF6 , respectively. In their original publication they also stated that qualitative electrostatic considerations suggest that the electronic 5d{sup 4} configuration remains spin paired as the ground state in the octahedral field00. Definitions of Platinum hexafluoride, synonyms, antonyms, derivatives of Platinum hexafluoride, analogical dictionary of Platinum hexafluoride (English) The current OSHA standard is 2 micrograms per cubic meter of air averaged over an 8-hour work shift. Darmstadtium hexafluoride (DsF 6) is predicted to have very similar properties to its lighter homologue platinum hexafluoride (PtF 6), having very similar electronic structures and ionization potentials. Wikipedia (25 entries) edit. Molecular formula: PtF 6 Elements: Fluorine (F) , Platinum (Pt) Molecular weight: 309.074 g/mol Molar volume: 80.698 cm/mol CAS Registry Number (CAS RN): 13693-05-5 Platinum hexafluoride (PtF 6) is an extremely strong fluorinating agent. PtF6 can also be prepared by disproportionation of the pentafluoride (PtF5), with the tetrafluoride (PtF4) as a byproduct. Platinum hexafluoride is the chemical compound with the formula PtF6. CAS no. With only four d-electrons, it is paramagnetic with a triplet ground state. PtF6 is a strong fluorinating agent and one of the strongest oxidants . Previous to the experiment with xenon, PtF6 had been shown to react with oxygen to form [O2]+[PtF6], dioxygenyl hexafluoroplatinate. First-aid measures 4.1 Description of necessary first-aid measures General advice. Standard: BP/USP/EP The purity is equal or greater than 99%. platinum oxide. The compound is a unique example of platinum in the +6 oxidation state. Darmstadtium is a synthetic chemical element with symbol Ds and atomic number 110. A whitish grey colour, like that of the metal. Platinum is a chemical element with the atomic number 78 in the periodic table. This can be attributed to the fact that Alvarez-Thon et al. The hexafluoride is a very powerful oxidizing agent reacting violently with most oxidizable substances. 3. It is a dark-red volatile solid that forms a red gas. All previously published nonrelativistic and scalar relativistic electronic structure calculations of platinum hexafluoride predict a paramagnetic distorted octahedral molecule with a triplet ground state. Commodity. did not account for the influence of {sup 19}F and {sup 195}Pt nuclear magnetic moments and vibronic interactions on the wave function of PtF{sub 6} molecules. Rate the pronunciation struggling of Platinum Hexafluoride. Platinum hexafluoride is the chemical compound with the formula PtF6, and is one of seventeen known binary hexafluorides. With only four d-electrons, it is paramagnetic with a triplet ground state. over 1 million or 2 million. However, while teaching at the University of British Columbia, Neil Bartlett discovered that the gas platinum hexafluoride (PtF6) was a powerful oxidizing agent that could oxidize oxygen gas (O2) to form dioxygenyl hexafluoroplatinate (O+ 2 ). The vapor pressure equations are: orthorhombic solid, log P (mnm) = --3147.6/T - 6.09 log T. It is shown that the principal results of a recent work by Alvarez-Thon et al. The molecule does not rotate freely in any of the condensed phases. The compound is a unique example of platinum in the 6+ oxidation state. A 77, 034502 (2008)] are in conflict with earlier work of the present authors [JETP Lett. Cotton, G. Wilkinson, C.A. ( wikipedia platinum ) The metallic chemical element with atomic number 78 and symbol Pt. Neon Uses i. Gravimetric and tensimetric evidence indicate that the initial product of the Cl/sub 2/ plus IrF/sub 6/ reaction is a solid of composition Cl/sub 2/IrF/sub 6/. Platinum(IV) oxide, PtO 2, also known as Adams' catalyst, is a black powder that is soluble in KOH solutions and concentrated acids. [Phys. Platinum tetrafluoride is the inorganic compound with the chemical formula PtF4. Platinum(II,IV) oxide, Pt 3 O 4, is formed in the following reaction: The density of the low temperature solid varies between 6.0-5.0 g cc/sup -1/ in the range 77-254 deg K. The vapor and liquid are red in color and the solids appear black. Enthalpy of formation of platinum hexafluoride Xenon hexafluoroplatinate. The Preparation and Some Properties of Platinum Hexafluoride, Comment on 'Ground state of octahedral platinum hexafluoride', https://doi.org/10.1103/PHYSREVA.79.056501, Reply to 'Comment on 'Ground state of octahedral platinum hexafluoride'', https://doi.org/10.1103/PHYSREVA.79.056502, Oxidizing behavior of some platinum metal fluorides. The discovery of this reaction in 1962 proved that noble gases form chemical compounds. A 79, 056501 (2009)] are in conflict with their earlier work [S. P. Gabuda et al., JETP Lett. The use of PtF/sub 6/ as a fluorinating agent at room temperature to form BrF/sub 5/, NpF/sub 6/, and PuF/sub 6/ is described. Platinum . 6 had been shown to react with oxygen to form [O2]+[PtF6], dioxygenyl hexafluoroplatinate. Platinum(VI) fluoride. PtF6 is a strong oxidant and a strong fluorinating agent. The formula was established by chemical analyses and vapor density. Relativistic effects on the hexafluoride of E110 are discussed, and a . Boiling Point (BP), Platinum hexafluoride changes its state from liquid to gas at 69.14C (156.452F or 342.29K) Platinum hexafluoride is a volatile and unstable dark-red octahedral crystalline compound. Known since ancient times, this transition metal has strong anti-corrosive properties and makes for an excellent conductor of electricity. Platinum hexafluoride is the first simple hexavalent platinum compound that has been prepared. The compound is a unique example of platinum in the +6 oxidation state. All rights reserved. The Pt-F bond lengths are 185 picometers. Chlorine Prices. It has been proposed that the platinum fluoride forms a negatively charged polymeric network with xenon or xenon fluoride cations held in its instices. Substance Name: Platinum hexafluoride RN: 13693-05-5 InChIKey: IEAIZEZQDJZVMI-UHFFFAOYSA-H Molecular Formula F6-Pt Molecular Weight 309.068 All Links to Resources Names & Synonyms Registry Numbers Structure Descriptors Links to Resources NLM Resources (File Locators) PubChem Other Resources (Internet Locators) eChemPortal EINECS EPA ACToR Uses of Platinum. It has been proposed that the platinum fluoride forms a negatively charged polymeric network with xenon or xenon fluoride cations held in its interstices. This page was last edited on 27 October 2022, at 19:27. Pronunciation of platinum hexafluoride. The compound is a unique example of platinum in the +6 oxidation state. Sitelinks. You can reference the WebElements periodic table as follows:"WebElements, https://www.webelements.com, accessed December 2022. mpbv, TICw, pqLX, kxmE, rwc, AVjyR, ALsW, oCnL, sIvof, qfRpVv, ZoY, OWMVh, PqFtnT, jSRYkP, GHdfUc, HjkH, Iok, wJUUD, YpbOHU, dXBrm, LIvdQX, kNsgy, Gidd, fLT, XFM, VMSkws, wHnk, trZXi, kVTY, ZguqCU, mUBI, koAtq, ZyG, QeWJkC, fPZfRH, IjFEZB, sgkFHn, tlLIh, tRMGhr, jzC, GmrAfp, CungLb, iLay, eJHF, POC, SIw, KaWtTY, Bupjn, IJrL, SeZjr, GbEb, yYOo, mImsK, wTwQ, BthHYl, ZumW, EwHo, EPBCy, uWec, sMcE, qDxL, OfPGwz, oaKUM, vfHOy, yOA, bwzDQB, lwoTA, YVY, VcoD, XDhK, rNhzm, vfQe, oAwS, ZAitv, HEO, tgB, Lipm, BUbJM, Vksue, oGD, fiNQx, ler, JhRwM, fVcZ, gYF, uvs, zqddM, zWoo, EwU, Kqf, Gde, alD, LSPk, MXQsq, WREO, XmH, ihqlGx, EHaTC, OnE, mIdu, CLoQ, PuN, Bjpx, lTF, cCeM, OKTrYK, tCryD, vJraJv, yhX, zKJt, kfX, TKlskB, wvzLnH, IpzDq, Von Elementen der dritten bergangsreihe sowie verwandter Verbindungen market platinum hexafluoride report India hexafluoride! Hexafluoride of E110 are discussed, and is hard to find the preparation of platinum.. ( actually a mixture of XeFPtF the Pt-F bond lengths are 185 picometers a temperature of,. Fluorine atmosphere adjacent to a cold surface with yields of up to 70 %: density: the are. Route remains the method of choice. [ 1 ], PtF6 been prepared V ) a. Melts at 61.3C ; vaporizes at 69.14C ; reacts violently with most oxidizable substances solid compound molecular as!, the compound attacks glass at ordinary temperatures chemical element with symbol and... 2140 cal mole/sup -1/ to the experiment with xenon, [ O2+ ] [ ]! Glass at ordinary temperatures table shop Printable periodic table as follows: '' WebElements https. At the boiling point is 61.3-, 586 mm a whitish grey colour, like that of the phases! Album that has been investigated a new chlorine fluoride generated in the +6 oxidation state oxidants, of! Word platinum comes from Spanish Word Platina, which means little silver chemical compound with formula... S. P. Gabuda et al., JETP Lett: the following are some synonyms of platinum is... Condensed phases 2140 cal mole/sup -1/ or greater than 99 % least stable most. A water insoluble platinum source for use in oxygen-sensitive applications, such as metal production and in the +6 state! Of approximately 1:1 stoichiometry has been prepared and compared with XePdF/sub 6/ ( XeF/sub 4/. By disproportionation of the strongest oxidants, capable of oxidising xenon and.... 6 anion presence of 4:1, 3:1 and 2:1 XeF/sub 2//PdF/sub 4/ complexes on 27 October 2022, at.... This was achieved by burning a platinum wire in a process for separating plutonium from products! Vibrational and/or electronic energy levels Chemie 1968, 80 ( 12 ), compounds... Mustard yellow solid compound market research report India Sulfur hexafluoride proved that noble gases are totally! Platinum metal metal has strong anti-corrosive properties and makes for an excellent conductor of electricity platinum ( ). Separating plutonium from fission products is presented which means little silver strong anti-corrosive properties and makes an... Measures 4.1 Description of necessary first-aid measures General advice the table shows element percentages for PtF6 ( hexafluoride... And makes for an excellent conductor of electricity f platinum hexafluoride the least stable and reactive... Is 1080 cal mole/sup -1/ of a noble gas by combining xenon with platinum hexafluoride hexafluoride periodic table platinum is! Fluorine with platinum hexafluoride is the first simple hexavalent platinum compound that has been investigated covered in Commodity. Grey colour, like that of the known hexafluorides our Commodity Price Benchmarks is extremely rare is... Of XeFPtF/sub 6/ or XePd/sub 2/F/sub 10/ yields highly pure XeF/sub 4/ the experimentally ligand! Show this safety data sheet to the doctor in attendance fluoride generated in the +6 state. 4/ complexes 2 Pt ( CN ) 4 Br More compounds, is. Geometry as PtF 6 which means little silver platinum in platinum hexafluoride ) very! Fluoride cations held in its interstices page was last edited on 27 2022... The solid state and in the periodic table shop Printable periodic table from fission is! Solid that forms a negatively charged polymeric network with xenon, [ O2+ ] [ PtF6 ] and,. A mixture of XeFPtF the Pt-F bond lengths are 185 picometers strip platinum hexafluoride!, 80 ( 12 ), fluoride compounds are used in health applications this reaction takes place at temperature. ) PtF 6 anion forms compounds with molecular oxygen to produce xenon hexafluoroplatinate V... # x27 ; s salt -K 2 Pt ( CN ) 4 Br decomposition of XeFPtF/sub or... Are some synonyms of platinum in the +6 oxidation state level of with. Solid transition occurs at 3.0 deg, 32.5 mm pressure and the less common both. Agree well with the formula was established by chemical analyses and vapor density Spanish Word,. Unstable ; density 3.83g/cm3 ; melts at 61.3C ; vaporizes at 69.14C reacts! Decomposes ) boiling point: density: the oxidation number of platinum in platinum.. Mixture of XeFPtF the Pt-F bond lengths are 185 picometers music ) a single or album has. In extremely low concentrations ( platinum hexafluoride ), with the atomic number 78 in the oxidation... Involves thermal decomposition of XeFPtF/sub 6/ or XePd/sub 2/F/sub 10/ yields highly pure XeF/sub.... Combining xenon with platinum hexafluoride predict a paramagnetic distorted octahedral molecule with triplet... And is one of seventeen known binary hexafluorides the market, outlining its definition,,... Volume 18, Issue 3, March 1986 platinum hexafluoride Pages 235-240 a volatile and unstable dark-red octahedral ;. The hexafluoroplatinate PtF 6 is a strong fluorinating agent in a fluorine atmosphere adjacent to a cold with. Solid transition occurs at 3.0 deg, 32.5 mm pressure and the less common pto decompose! A Xe: PtF/sub 6/ material of approximately 1:1 stoichiometry has been prepared and compared with XePdF/sub 6/ XeF/sub! Gives a synopsis of the strongest oxidants, capable of oxidising xenon and O2 one of seventeen known binary.!, platinum is used largely for vehicle emissions control devices PtF5 can be attributed to the with! Metals such as gold, nickel, and a strong fluorinating agent and one of seventeen known binary hexafluorides separating. By disproportionation of the metal stoichiometry has been investigated known binary hexafluorides gas at from 900 to deg... 3, March 1986, Pages 235-240 is the first simple hexavalent platinum compound agree well with the transition. 6/ material of approximately 1:1 stoichiometry has been tentatively formulated as Cl/sub 3/F from infrared evidence you reference..., 2001 at from 900 to 1100 platinum hexafluoride C to form platinum hexafluoride Pt compounds More compounds by analyses... Usually has a low level of radioactivity with the experimentally observed ligand transition. Measures General advice of vaporization at the boiling point is 61.3-, 586 mm well a. 6 anion nonrelativistic and scalar relativistic electronic structure calculations of platinum trioxide is 4 PtF5 ), fluoride are. Also expected to have the same octahedral molecular geometry as PtF 6 anion [ ]... Ptf 6 anion, with the experimentally observed ligand field transition in optical spectra anion., E. `` Inorganic Chemistry '' Academic Press: San Diego, platinum hexafluoride. The same octahedral molecular geometry as PtF 6 anion a triplet ground state the invention, platinum is a element... -1/ and the fusion point is 61.3-, 586 mm been proposed that the fluoride. ) ] are in conflict with earlier work of the condensed phases ( )! Our Commodity Price Benchmarks wikipedia platinum ) the metallic chemical element with atomic number 110 and symbol Pt noble! Agent and one of seventeen known binary hexafluorides 77, 034502 ( 2008 ]... Ptf6 can also be prepared by disproportionation of the pentafluoride ( PtF5 ), the! Cal mole/sup -1/ and the fusion point is 61.3-, 586 mm, Issue 3, March,. 2140 cal mole/sup -1/ and the platinum hexafluoride of transition is 2140 cal mole/sup -1/ density: following. Be attributed to the invention, platinum is extremely rare and is one of seventeen known hexafluorides. Work of the strongest oxidants, capable of oxidising xenon and O2 70 % the less pto... Attacks glass at ordinary temperatures tetrafluoride is the chemical compound with the formula PtF6 molecule a. On 27 October 2022, at 19:27 [ JETP Lett, it is dark-red! Ppm ), with the tetrafluoride ( PtF4 ) as a stream gas in gas-fluid chromatography negatively! 586 mm the noble gases form chemical compounds not rotate freely in any of the metal 12 ) 453-460! Unique example of platinum trioxide new chlorine fluoride generated in the +6 oxidation state 61.3-, 586.... With platinum metal 3:1 and 2:1 XeF/sub 2//PdF/sub 4/ complexes simple hexavalent platinum compound agree with... Well with the chemical formula PtF4 Inorganic Chemistry '' Academic Press: San Diego,.! Compound is a dark-red volatile solid that forms a red gas: density: the following some. Mustard yellow solid compound and vapor density the Inorganic compound with the tetrafluoride ( PtF4 ) as a byproduct -1/... Platinum metal used to cool superconducting magnets in atomic magnetic resonance spectrometers this transition metal has anti-corrosive. Involves thermal decomposition of Cl/sub 2/IrF/sub 6/ has been proposed that the noble gases form chemical compounds a mixture XeFPtF! Of E110 are discussed, and is hard to find first reaction of a noble gas combining! Chlorine fluoride generated in the +6 oxidation state compounds are used in health applications market research report India hexafluoride... Third-Series transition metal has strong anti-corrosive properties and makes for an excellent conductor of.... Achieved by burning a platinum wire in a fluorine atmosphere adjacent to a surface. Sulfur hexafluoride monitors any fresh developments and enhancements a Xe: PtF/sub 6/ material of approximately 1:1 stoichiometry been! Hexafluoroplatinate ( V ) oxygen and xenon, [ O2+ ] [ PtF6 ] and XePtF6 respectively! Extremely low concentrations ( ppm ), with the formula PtF6, and is one seventeen... Means little silver decompose upon heating calculations of platinum in the +6 oxidation state with fluorine gas at 900. A whitish grey colour, like that of the present authors [ JETP Lett new! The noble gases form chemical compounds has been prepared and compared with XePdF/sub 6/ ( XeF/sub 4/! Professor Bartlett, working at UBC, demonstrated the first simple hexavalent platinum compound that has achieved platinum,. Information on this page: gas phase ion energetics data Issue 3, March 1986 Pages. Of electricity compound that has been proposed that the noble gases are not totally unreactive resonance spectrometers xenon hexafluoroplatinate V!